Prof. Dr. Manfred Scheer

Professor and Chair of Inorganic Chemistry, University of Regensburg (Germany)

Homepage: http://www.chemie.uni-regensburg.de/Anorganische_Chemie/Scheer/index.html
Tel. +49 (0) 941 943-4440
Fax. +49 (0) 941 943-4439
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Current research interests:

• Unsubstituted main-group elements as ligands
• supramolecular chemistry of polypnicogen complexes
• mixed main-group-element compounds
• highly reactive compounds with element– transition-metal multiple bonds
• molecular precursors for metastable solids, nanoparticles, and materials

The title is awarded by the Scientific Council of the Institute on its special ceremonial meeting (22.06.2012)

Publications in collaboration with the Nikolaev Institute of Inorganic Chemistry

1. 1 Gröger, H. R. Kalbitzer, M. Pronold, D. Piryazev, M. Scheer, J. Wachter, A. Virovets and M. Zabel
   Novel Metal-Organic Frameworks Incorporating [Cp°₂Mo₂P₄S] (Cp° = 1-t-Bu-3,4-Me₂C₅H₂), P₄S₃ and Cu₂I₂ Building Blocks
   Eur. J. Inorg. Chem. 2011, P. P. 785–793
2. 2 Biegerl, D. Piryazev, M. Scheer, J. Wachter,A. Virovets, M. Zabel
   P₄S₃and P,P’ or N,N’ Donors as Competitive Building Blocks in Copper(I) Coordination Polymers
   Eur. J. Inorg. Chem. – 2011. –P.4248–4255
3. 3 A. Pushkarevsky, S. N. Konchenko, M. Zabel, M. Bodensteiner and M. Scheer
   Dimerization of pentanuclear clusters [Fe₃Q(AsMe)(CO)₉] (Q = Se, Te) as conversion pathway to novel cubane-like aggregates
   Dalton Trans. 2011, 40, 2067 – 2074
4. 4 Dielmann, M. Sierka, A. V. Virovets and M. Scheer
   Novel Pathway to Extended Polyphosphorus Frameworks
   Angew. Chem. 2010, 122, 7012 - 7016
   Angew. Chem. Int. Ed. 2010, 49, 6860 – 6864
5. 5 Scheer, A. Schindler, J. Bai, B. P. Johnson, R. Merkle, R. Winter, A. V. Virovets, E. V. Peresypkina, V. A. Blatov, M. Sierka, and H. Eckert;
   Structures and Properties of Spherical 90-Vertex Fullerene-like Nanoballs
   Chem. Eur. J., 2010, 16, 2092-2107
6. 6 Trinh, M. Bodensteiner, A. V. Virovets, E. V. Peresypkina, M. Scheer, S. M. Matveev and A. Y. Timoshkin;
   Chelating ionic versus bridged molecular structures of group 13 metal complexes with bidentate ligands
   Polyhedron 2010, 29, 414 – 424
7. 7 J. Gregoriades, B. K. Wegley, M. Sierka, E. Brunner, C. Gröger, E. V. Peresypkina, A. V. Virovets, M. Zabel, M. Scheer;
   One-Dimensional Polymers Based on Silver(I) Cations and Organometallic cyclo-P₃ Ligand Complexes
   Chem. Asian J. 2009, 4, 1578 – 1587
8. 8 Scheer, A. Schindler, C. Gröger, A. V. Virovets and E. V. Peresypkina;
   A spherical molecule with a carbon-free I_h-C₈₀ topological framework
   Angew. Chem. 2009, 121, 5148 - 5151
   Angew. Chem. Int. Ed. 2009, 48, 5046 – 5049
9. 9 Welsch, B. Nohra, E. V. Peresypkina, Ch. Lescop, M. Scheer and R. Réau;
   Chemistry of Bridging Phosphanes: A Comparative Study within Cu^I-Ag^I-Au^I Triad-based Homonuclear-dimers
   Chem. Eur. J. 2009, 15, 4685 – 4703
10. 10 A. Pushkarevsky, D. A. Bashirov, A. V. Litke, A. V. Virovets, N. V. Kurat'eva, M. Scheer, S. N. Konchenko;
    Isolobal Replacement of the Metal Fragment in [Fe₃(µ₃-Q)(µ₃-AsCH₃)(CO)₉] (Q = Se and Te): Synthesis and Structures of a Number of Fe-Ir and Fe-Rh Clusters Simultaneously Containing a Chalcogen and Arsenic
    Russ. J. Coord. Chem. 2008, 34, 871 – 883
11. 11 Welsch, L. J. Gregoriades, M. Sierka, M. Zabel, A. Virovets and M. Scheer;
    Unusual Coordination Behaviour of P_n-Ligand Complexes with Tl⁺
    Angew. Chem. 2007, 119, 9483 - 9487
    Angew. Chem. Int. Ed. 2007, 46, 9323 – 9326
12. 12 Scheer, A. Schindler, R. Merkle, B. P. Johnson, M. Linseis, R. Winter, C. E. Anson and A. Virovets;
    Fullerene C₆₀ as an Endohedral Molecule within an Inorganic Supramolecule
    J. Am. Chem. Soc. 2007, 129, 13386-13387
13. 13 A. Pushkarevsky, S. N. Konchenko and M. Scheer;
    Synthesis, Structure and Isomerism of the [Fe₃Pt(µ₄-Q)(CO)₉(dppm)] Clusters (Q = Se, Te; dppm = Ph₂PCH₂PPh₂)
    J. Cluster Science 2007, 18, 606 – 617
14. 14 Scheer, L. J. Gregoriades, A. V. Virovets, W. Kunz, R. Neueder and I. Krossing;
    Reversible Formation of Polymeric Chains by Coordination of Pentaphosphaferrocene with Silver(I) Cations
    Angew. Chem. 2006, 118, 5818-5822
    Angew. Chem. Int. Ed. 2006, 45, 5689-5693
15. 15 J. Gregoriades, H. Krauss, J. Wachter, A. V. Virovets, M. Sierka and M. Scheer;
    The Potential of a cyclo-As₃ Ligand Complex in Supramolecular Chemistry
    Angew. Chem. 2006, 118, 4295-4298
    Angew. Chem. Int. Ed. 2006, 45, 4189-4192
16. 16 Scheer, J. Bai, B. P. Johnson, R. Merkle, A. V. Virovets and C. E. Anson;
    Fullerene-like Nanoballs formed by Pentaphosphaferrocene and CuBr
    Eur. J. Inorg. Chem. 2005, 20, 4023-4026
17. 17 Scheer, M. Kaupp, A. V. Virovets und S. N. Konchenko;
    Elemental Gallium as a Source of Novel Subvalent Gallium Units in Unprecedented Ga/Rh Clusters
    Angew. Chem. 2003, 115, 5237-5240
    Angew. Chem. Int. Ed. 2003, 42, 5083-5086
18. 18 N. Konchenko, N. A. Pushkarevsky und M. Scheer;
    First Examples of Electrophilic Addition to a Fe₂Q Face of [Fe₃(µ₃-Q)(CO)₉]^2- (Q = Se, Te) - Synthesis and Characterisation of [MFe₃(µ₃-Q)(CO)₉Cp*] and [IrFe₂(µ₃-Q)(CO)₇Cp*] (M = Rh, Ir; Cp* = η⁵-C₅(CH₃)₅)
    J. Cluster Science 2003, 14, 299 – 312
19. 19 Bai, A. V. Virovets und M. Scheer;
    Synthesis of Inorganic Fullerene-like Molecules
    Science, 2003, 300, 781-783
20. 20 N. Konchenko, N. A. Pushkarevsky, A. V. Virovets und M. Scheer;
    Reactions of [Fe₃(µ₃-Q)(CO)₉] (Q = Se, Te) with organic and organometallic dihalides of group 15 elements - An approach to functionalised clusters
    J. Chem. Soc., Dalton Trans., 2003, 581-585
21. 21 N. Konchenko, N. A. Pushkarevsky und M. Scheer;
    Synthesis and structure of the novel mixed Sb/Se and Sb/Te-containing Iron Carbonyl Clusters [Fe₃(µ₃-Y)(µ₃-SbMes)(CO)₉] (Y = Se, Te) and [Fe₃(µ₃,η²:η¹-SeSbMes)(µ₃-SbMes)(CO)₁₀]
    J. Organometal. Chem., 2002, 658, 204-209
22. 22 Bai, A. V. Virovets und M. Scheer;
    Pentaphosphaferrocene as a Linking Unit for the Formation of One- and Two-Dimensional Polymers
    Angew. Chem., 2002, 114, 1808-1811
    Angew. Chem. Int. Ed., 2002, 41, 1737-1740
23. 23 Scheer, V. P. Fedin, Yu. V. Mironov und V. E. Fedorov;
    Zum Reaktionsverhalten von Molybdän-, Wolfram- und Rheniumchalkogeniden mit Phosphorpentachlorid (russ.)
    Zh. Neorg. Khim., 36 (1991) 1382 – 1384
24. 24 Scheer, T. T. Nam, K. Schenzel, E. Herrmann, P. G. Jones, V. P. Fedin, V. N. Ikorski und V. E, Fedorov;
    Das Reaktionsverhalten von Phosphorpentahalogeniden mit Übergangsmetallcarbonylverbindungen. IV [1,2] - Das Reaktionsverhalten gegenüber [CpM(CO)₃]₂ ( M = Cr, Mo, W) - Die Kristallstruktur von CpCrCl₂CH₃CN
    Z. Anorg. Allg. Chem., 591 (1990) 221 – 229
25. 25 Scheer, T. T. Nam, E. Herrmann, V. P. Fedin und V. E. Fedorov;
    Die Reaktion von Phosphorpentabromid mit Chromiumhexacarbonyl in Acetonitril
    Z. Chem., 30 (1990) 451 – 452
26. 26 Scheer, T. T. Nam, E. Herrmann, V. P. Fedin, V. N. Ikorski und V. E. Fedorov;
    Das Reaktionsverhalten von Phosphorpentahalogeniden mit Übergangsmetallcarbonylen. III [1,2] - Die Reaktion von PBr₅ mit Metallcarbonylen des Molybdäns und Wolframs
    Z. Anorg. Allg. Chem., 589 (1990) 214 - 220
27. 27 P. Fedin, M. Scheer, Yu. I. Mironov, A. G. Klimenko, S. M. Ishikaev, V. P. Shaburova und V. E. Fedorov;
    Eine neue Methode zur Darstellung Chlor-enthaltender Hochtemperatursupraleiter YBa₂Cu₃O_7-xCl_y
    Isv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim., 1990 (1) 134 – 141
28. 28 P. Fedin, M. N. Sokolov, O. A. Geras'ko, M. Scheer, V. E. Fedorov, A. V. Mironov, und L. Slovokhotov und Yu. T. Strutchkov;
    New synthetic Route to W₃S₄⁴⁺ clusters: preparation and structure of [W₃(µ-S)(µ-S)₃(S₄)₃(H₂O)₃]^2-
    Inorg. Chim. Acta, 165 (1989) 25 – 26
29. 29 G. Klimenko, S. M. Ishikaev, Yu. I. Mironov, V. P. Fedin, V. E. Fedorov und M. Scheer;
    Synthese und Eigenschaften einphasiger Verbindungen des Typs YBa₂Cu₃O_7-yCl_x (russ.)
    Supraleiter: Physik, Chemie, Technik, 2 (1989) 141 – 145
30. 30 Scheer, A. Kolbe, E. Herrmann, V. P. Fedin, V. E. Fedorov, V. N. Ikorski und M. A. Fedotov;
    Zur Reaktivität von PCl₅ mit Übergangsmetallcarbonylen und -phosphiden
    Z. Anorg. Allg. Chem., 567 (1988) 111 – 121
31. 31 Scheer, V. P. Fedin, V. E. Fedorov und B. A. Kolosov;
    Die Synthese eines Thiobromides des Wolframs (WS₂Br)_n (russ.)
    Koord. Khim., 14 (1988) 856
32. 32 P. Fedin, Yu. V. Mironov, M. Scheer und V. E. Fedorov;
    Synthese mehrkerniger Thiokomplexe des Molybdäns und Wolframs (russ.)
    Zh. Vsesojusn. Khim. Obshch., 32 (1987) 106 – 107
33. 33 Scheer, V. P. Fedin, V. E. Fedorov, M. A. Fedotov und P. P. Semjanikov;
    Zur Reaktivität von Telluriden des Niobs, Molybdäns, Wolframs und Rheniums mit Phosphorpentachlorid (russ.)
    Zh. Neorg. Khim., 38 (1987) 1769 – 1771