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Prof. Rosa Llusar Barelles

Full Professor of Physical Chemistry, Departamento de Química Física i Analítica, Avda.

Sos Baynat s/n, Universitat Jaume I, Castelló de la Plana , 12071, Spain
Phone: 34-64-345700
Fax: 34-6-345654

Research interest

  • Development of molecular materials based on cluster complexes with tecnologial applications (catalysis, non-linea optics, molecular electronics, constrast agents etc.)
  • Reaction mechanisms in transition metal cluster chalcogenides combining experimental and theoretical methods

The title is awarded by the Scientific Council of the Institute on its special ceremonial meeting (22.06.2012)

Publications in collaboration with the Nikolaev Institute of Inorganic Chemistry

  1. “Coordination of Phenylsulfinate PhSO2- to Mo3MS4 4+ (M= Ni, Pd)”

Maxim N. Sokolov, Rita Hernández-Molina, Danil N. Dybtsev, Elena V. Chuvarova, Sergei F. Solodovnikov, Natalia V. Pervukhina, Cristian Vicent, Rosa Llusar, Vladimir Fedin. Zeitschrift fur Anorganische und Allgemeine Chemie 2002, 628, 2335-2339.

  1. “New coordination cyano-bridged polymers based on tetranuclear rhenium chalcocyanide clusters and copper (II) ammonia complexes”

Yu V. Mironov, O. A. Efremova,  V. E. Fedorov, O. Oeckler, A. Simon., C. Vicent,  R. Llusar Russian Chemical Bulletin  2003, 8, 1698-1701

  1. “Novel inorganic ionic compounds based on the Re6 chalcocyanide cluster complexes: synthesis and crystal structures of [Cu(trien)NH3]2[Re6S8(CN)6]·7H2O, [Cu(trien)NH3]2[Re6Se8(CN)6] and [Cu(trien)NH3]2[Re6Te8(CN)6]·H2O” Konstantin A. Brylev, Nikolai G. Naumov, O., Gabriel Peris, Rosa Llusar, Vladimir. E. Fedorov

Polyhedron  2003, 22, 3383-3387.

  1. “Reactivity of Mo3PdS44+ Cluster: Evidence for New Ligands PhP(OH)2 and Ph2P(OH) and Structural Characterization of [Mo3(Pd(PPh3)S4(H2O)5Cl4] · 0.5CH3OH · 3H2O”

Maxim N. Sokolov, Elena V. Chuvarova, Alexander V. Virovets, Rosa Llusar and Vladimir Fedin J. Clust. Sci. 2003, 14, 227-234.

5.“Coordination of Bismuth(III) to Cucurbit[8]uril. Preparation and X-ray Structure of [{Bi(NO3)(H2O)5}2(Q8)[Bi(NO3)3(H2O)4]2[Bi(NO3)5]2·Q8·19H2O” Maxim N. Sokolov, Tatyana V. Mitkina, Olga A. Gerasko, Vladimir Fedin, Alexander V. Virovets and Rosa Llusar Z. Anorg. Allg. Chem.  2003, 2440-2442.

  1. “Supramolecular Chemistry based on [W3S4(H2O)6Cl3]+ - a Versatile Building Block” Maxim N. Sokolov, Olga A. Gerasko, Danil N. Dybtsev, Elena V. Chuvarova, Alexander Virovets, , Cristian Vicent, Rosa Llusar , Dieter Fenske and Vladimir Fedin Eur. J. Inorg. Chem. 2004, 63-68.
  2. “Aqueous solution chemistry of [Mo3CuSe4]n+ (n= 4, 5) and [W3CuQ4]5+ (Q= S, Se) clusters” Rita Hernández-Molina, Maxim Sokolov, Pedro Esparza, Cristian Vicent, Rosa Llusar Dalton Trans. 2004, 6, 847-851.
  3. “Synthesis and crystal structures of cyano-bridged cluster-metal layered coordination polymers [Cu(dien)]3[W4Te4(CN)12] · 12H2O and [Ni(en)]3[W4Se4(CN)12] · 7.5H2O”

Irina V. Kalinina, Alexander V. Virovets, Fedor M. Dolgushin, Mikhail Yu. Antipin, Rosa Llusar, Vladimir Fedin Inorg. Chim. Acta. 2004, 357, 3390-3396.

  1. “Inclusion of nickel (II) and copper (II) complexes with aliphatic polyamines in cucurbit[8]uril” T. V. Mitkina, D. Yu. Naumov, O. A. Gerasko, F. M. Dolgushin, C. Vicent, R. Llusar, M. N. Sokolov and V. P. Fedin Russian Chemical Bulletin, 2004, 53, 2519-2524.
  2. “Preparation and properties of the full series of cuboidal clusters [MoxW4-xSe4(H2O)12]n+ (n=4-6) and their derivatives” M. Sokolov, P. Esparza, R. Hernandez-Molina, A. Mederos, J. G. Platas, J. A. Gavin, R. Llusar, C. VicentInorg. Chem.  2005, 44, 1132-1141.

 “[Mo3ReS4(O)2(S2P(OEt)2)5]: an example of chalcogenide cluster with a highly oxidized Mo3ReS49+ core” Rosa Llusar, Maxim Sokolov and Cristian Vicent

Comptes Rendus Chimie- special issue, 2005, 8, 1815-1819.

  1. “A New series of homologous cluster complexes [Mo3(M’EPh3)Q4Cl4(H2O)5] (M’= Ni, Pd; E= P, As; Q= S,Se)” Maxim N. Sokolov, Elena V. Chubarova, Rita Hernández-Molina, Maria Clausén, Dimitri Yu. Naumov, Cristian Vicent, Rosa Llusar, Vladimir P. Fedin. Eur. J. Inorg. Chem. 2005, 2139-2146.
  2. “Synthesis and Reactivity of W3Te7 4+ Clustes and Chalcogen Exchange in the M3Q7 (M= Mo. W; Q= S, Se, Te) Cluster Family”

Maxim N. Sokolov, Pavel A. Abramov, Artem L. Gushchin, Irina V. Kalinina, Dmitry Y. Naumov, Alerxander V. Virovets, Eugenia V. Presesypkina, , Cristian Vicent, Rosa Llusar, Vladimir P. Fedin. Inorg. Chem. 2005, 44, 8116-8124.

  1. “A family of Oxo-Chalcogenide Molybdenum and Tungsten Complexes, (n-Bu4N)2[M2O2(m-Q)2(dmit)2] (M = Mo, W; Q = S, Se): New Synthetic Entries, Structure and Gas-Phase” Rosa Llusar, Sonia Triguero, Cristian Vicent, Maxim N. Sokolov, Benoît Domercq and Marc Fourmigué Inorg. Chem., 2005, 44, 8937-8946.
  2. “Synthesis, structure and reactivity of cuboidal-type cluster aquo complexes with W3PdS44+ core” Rita Hernández-Molina, Irina Kalinina, Maxim Sokolov, María Clausen, Javier Gonzalez Platas, Cristian Vicent, Rosa Llusar, Dalton Trans. 2007, 550-557.
  3. “Structural Diversity in Charge Transfer Salts Based on Mo3S7 and Mo3S4Se3 Clusters Complexes and Bis(ethylendithio)tetrathiafulvalene (ET)”

Antonio Alberola, Rosa Llusar, Sonia Triguero , Cristian Vicent, Maxim N. Sokolov, Carlos J. Gomez-Garcia Chem.  Materials.  2007, 17, 3440-3450.

  1. “Distinctive unimolecular gas-phase reactivity of [M(en)2]2+ (M = Ni, Cu) dications and their inclusion complexes with the macrocyclic cavitand cucurbit[8]uril “

Tatiana Mitkina, Vladimir Fedin  Rosa Llusar, Ivan Sorribes, Cristian Vicent

  1. Am. Mass Spec. 2007, 18, 1863-1872.
  2. “Studies on Iron-Containing Chalcogenide Clusters with Core M3FeQ4 (M =Mo, W; Q =S, Se)”Rita Hernández-Molina, Irina V. Kalinina, Maxim N. Sokolov, Rosa Llusar, Gabriel Peris.

Synt. and React. in Inorg. Metal-Org. and Nano-Metal Chem. 2007, 37, 765-770.

  1. “Tetranuclear lanthanide aqua hydroxo complexes with macrocyclic ligand cucurbit[6]uril:two structural types of core”

Olga Gerasko, Ekaterona A. Mainicheva, Marina I. Naumova, Olga P. Yurjeva, Cristian Vicent , Antonio Alberola, Rosa Llusar y Vladimir P. Fedin Eur. J. Inorg. Chem  2008, 416-424.

  1. “Heterometallic cuboidal clusters M3M’Q4 (M=Mo, W; M’=Sn, Pb, As, Sb; Q=S, Se): from coordination compounds to supramolecular adducts”

Rita Hernández-Molina, Irina V. Kalinina, Pavel A. Abramov, Maxim Sokolov, Alexander V. Virovets, Javier G. Platas, Rosa Llusar, Victor Polo, Cristian Vicent y Vladimir P. Fedin Inorg. Chem.  2008, 47, 306-314.

  1. “Unexpected Transformation of a diamagnetic Mo3(μ3-S)(μ-S)3 to a Paramagnetic Mo3(μ3-S)2(μ-S)3 Cluster Core by Reaction of [Mo3S4(dppe)3Br3](PF6) with tBuSNa”

Pavel A. Petrov, Alexander V. Virovets, Antonio Alberola, Rosa Llusar, Sergey N. Konchenko Dalton Trans. 2010, 39, 8875-8877

  1. “Cuboidal Mo3S4 and Mo3NiS4 Complexes Bearing Dithiophosphates and Chiral Carboxylate Ligands: Synthesis, Crysyal Structure and Fluxionality”

Rita Hernández-Molina, Javier Gonzalez-Platas, Konstantin A. Kovalenko, Maxim N. Sokolov, Alexandre V. Virovets, Rosa Llusar , Cristian Vicent

Eur. J. Inorg. Chem.  2011, 5, 683-693

  1. “First Heteroleptic Mo3S7 Clusters containing Non-innocent Phenanthroline Ligands.”

Artem Gushchin, Rosa Llusar, David Recatalá, Pavel Abramov

Russ. J. Inorg. Chem  2011,   submitted

  1. “Synthesis, molecular and electronic structure of an incomplete cuboidal Re3S4 cluster with C3 symmetry and an unusual quadruplet ground state”

Pavel A. Petrov, Alexander V. Virovets,Artem S. Bogomyakov,cRosa Llusar, Carlos J. Gómez-García,Víctor Polo and Sergey N. Konchenko

Chem. Commun  2011, submitted.

 

 

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